Di belakang Hamilton di posisi ketiga adalah pebalap Ferrari Sebastian Vettel, mengungguli wakil Red Bull Daniil Kvyat, kemudian Valtteri Botas dan Felipe Massa dari Williams.
Rosberg mencatatkan lap tercepat 1 menit 19,480 detik, sedangkan Hamilton 1 menit 19,668 detik, Sebastian Vettel 1 menit 19,850 detik, diikuti Daniil Kvyat 1 menit 20,398 detik.
Berikut hasil kualifikasi Formula 1 Meksiko mengutip laman resmi F1:
| Pos. | Driver | Team | Q1 | Q2 | Q3 | Laps |
| 1 | Nico Rosberg | Mercedes | 01:20.4 | 01:20.1 | 01:19.5 | 23 |
| 2 | Lewis Hamilton | Mercedes | 01:20.8 | 01:19.8 | 01:19.7 | 22 |
| 3 | Sebastian Vettel | Ferrari | 01:20.5 | 01:20.0 | 01:19.8 | 18 |
| 4 | Daniil Kvyat | Red Bull Racing | 01:20.8 | 01:20.5 | 01:20.4 | 21 |
| 5 | Daniel Ricciardo | Red Bull Racing | 01:21.2 | 01:20.8 | 01:20.4 | 23 |
| 6 | Valtteri Bottas | Williams | 01:20.8 | 01:20.5 | 01:20.4 | 26 |
| 7 | Felipe Massa | Williams | 01:21.4 | 01:20.6 | 01:20.6 | 26 |
| 8 | Max Verstappen | Toro Rosso | 01:21.0 | 01:20.9 | 01:20.7 | 28 |
| 9 | Sergio Perez | Force India | 01:21.0 | 01:20.7 | 01:20.7 | 21 |
| 10 | Nico Hulkenberg | Force India | 01:21.3 | 01:20.9 | 01:20.8 | 20 |
| 11 | Carlos Sainz | Toro Rosso | 01:21.0 | 01:20.9 | 20 | |
| 12 | Romain Grosjean | Lotus | 01:21.6 | 01:21.0 | 18 | |
| 13 | Pastor Maldonado | Lotus | 01:21.5 | 01:21.3 | 19 | |
| 14 | Marcus Ericsson | Sauber | 01:21.3 | 01:21.5 | 19 | |
| 15 | Kimi Räikkönen | Ferrari | 01:21.4 | 01:22.5 | 13 | |
| 16 | Fernando Alonso | McLaren | 01:21.8 | 10 | ||
| 17 | Felipe Nasr | Sauber | 01:21.8 | 12 | ||
| 18 | Alexander Rossi | Marussia | 01:24.1 | 10 | ||
| 19 | Will Stevens | Marussia | 01:24.4 | 9 |
Editor: Suryanto
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